public class PIIUser
{
    ...
    public int? LoyaltyUserDetailId { get; set; }
    [ForeignKey("LoyaltyUserDetailId")]
    public LoyaltyUserDetail LoyaltyUserDetail { get; set; }
    ...
}

public class LoyaltyUserDetail
{
    ...
    public int PIIUserId { get; set; }
    [ForeignKey("PIIUserId")]
    public PIIUser PIIUser { get; set; }
    ...
}

این لینک هم ببینید